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Bujold, Lois McMaster
Card, Orson Scott
Chalker, Jack L.
Heinlein, Robert A.
McKillip, Patricia A.
Nye, Jody Lynn
|Stereochemistry at a Glance
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Author: Jason Eames
Stereochemistry deals with the three-dimensional arrangement of atoms in molecules. All chemical reactions take place three dimensions and the spatial arrangement of those atoms can have a profound effect on the outcome of a chemical reaction. A good understanding of stereochemistry is, therefore, fundamental to any detailed appreciation and study of organic chemistry.
Based on the highly successful at a Glance series from Blackwell Publishing, this book provides a concise introduction and overview of stereochemistry for students studying chemistry and related courses at undergraduate level. It then reinforces that overview by presenting 49 fully worked out stereochemistry problems, presented in the familiar at a Glance double page layout. A further 98 supplementary problems, with abbreviated answers, are designed to help the undergraduate student rapidly develop the knack of thinking in three dimensions, and generate the confidence to apply their knowledge of stereochemistry in the classroom, the exam room or the laboratory.
Graphical presentation of information is central to the book. As befits such a visual subject, this facilitates the rapid assimilation and understanding of the basic concepts, principles and definitions of stereochemistry. Students using Stereochemistry at a Glance will find they have a resource with which they can quickly, economically and confidently acquire, regularly review and revise the basic facts that underpin stereochemistry.
|CRC Handbook of Optical Resolutions via Diastereomeric Salt Formation
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Optically active compounds are gaining ever-increasing importance in organic chemistry, both in the academic and the industrial arenas. The rational synthesis of the growing number of chiral chemicals, drugs, and natural products demands efficient methods for producing these compounds in an enantiomerically, highly pure form. Despite the available alternative techniques, optical resolution via Diastereomeric salt formation remains the most widely used method of preparing pure enantiomers.
The CRC Handbook of Optical Resolutions Via Diastereomeric Salt Formation is the first book to exclusively address this important organic chemical process. It provides fast, one-stop access to a wealth of information, including all of the available data on 100 resolving agents, a list of 500 optically active compounds available in bulk along with their suppliers, data on more than 3,500 resolutions, and 4,200 citations.
This handbook helps answer virtually any question that may arise during the development of a new resolution process.
Which resolving agent and solvent should I use under these conditions?
How can I separate the diastereoisomers?
How can I optimize a resolution process?
How do I determine enantiomeric purity?
Which supplier has the resolving agent I need?
For a racemate already resolved, what were the resolving agent, solvent, and relevant citation?
This is the first book to deal exclusively with all aspects of this important organic chemical process, both theoretical and practical. With an abundance of analyzed examples, this single, authoritative reference provides all of the information you need to perform, develop, and optimize optical resolutions via Diastereomeric salt formation
|Introduction to Stereochemistry and Conformational Analysis
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Author: Eusebio Juaristi
Stereochemistry remains an actively changing area of knowledge. Topics include chirality, the determination of absolute configurations, stereochemical descriptors, chiroptic properties, asymmetric synthesis, the resolution of racemates, confirmational analysis of both alkanes and heterocycles and much more. In addition to figures, equations and tables, it is profusely illustrated with examples both historical and current.
|Carbon-13 NMR Chemical Shifts in Structural and Stereochemical Analysis (Methods in Stereochemical Analysis)
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Author: Kalevi Pihlaja
The book concentrates in illustrating the applications of C-13 chemical shifts to structural and stereochemical analysis of a variety of organic, oranometallic and bio-organic compounds including dynamic NMR, the experimental conditions to determine and various multidimensional methods to assign the C-13 chemical shifts. First time a chemist who wants to employ C-NMR for solving a structural problem will find practically all necessary fundamental advice within the same covers. The book is a new volume in the successful series 'Methods in Stereochemical Analysis' and is geared towards scientists and students. It is limited mainly to alicyclic chemistry in order to make the explanations transparent and understandable to readers.
|Carbon-Carbon and Carbon-Proton Nmr Couplings: Applications to Organic Stereochemistry and Conformational Analysis (Methods in Stereochemical Analysis)
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Author: James L. Marshall
Brand: Brand: Vch Pub
This comprehensive survey of long-range carbon-proton (13C-1H) and carbon-carbon (13C-13C) couplings contains all the information needed to apply successfully this advanced method of instrumental analysis. It discusses the special considerations that apply particularly to the acquisition of carbon coupling data via Fourier transform NMR spectroscopy and refers to corresponding proton-proton couplings in cases where they apply to carbon-proton and carbon-carbon couplings. It also gives particular attention to the troublesome problem of determining the signs of carbon couplings.
- Used Book in Good Condition
|The Nuclear Overhauser Effect in Structural and Conformational Analysis, 2nd Edition
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Author: David Neuhaus
An authoritative review of the state of the art in the Nuclear Overhauser Effect-essential information for organic chemists, biochemists, biophysicists, and NMR spectroscopists
The field of NMR spectroscopy has seen tremendous growth in the last twenty years, particularly advances relating to Nuclear Overhauser Effect (NOE) spectroscopy-the most powerful technique for obtaining structural information on molecules in solution. Extensive and engaging, the Second Edition of the leading reference on the NOE is significantly updated to reflect the latest changes and new approaches in the field.
Neuhaus and Williamson provide an essential guide to the complexities and use of the NOE in a readily accessible, straightforward manner. Their practical handbook features a new chapter addressing the use of NOE data to calculate biomolecular structures. Chapters dealing with the kinetics of the NOE, the effects of exchange and internal motion, and applications of the NOE, are also extensively revised. Cross-referenced in remarkable depth, The Nuclear Overhauser Effect is organized into three main parts:
* Part I describes the theory of the Nuclear Overhauser Effect in a clear, comprehensive fashion
* Part II discusses the considerations involved in implementing NOE experiments, including full coverage of all necessary details for both new and established techniques
* Part III offers examples of how the NOE is used, including applications to defining molecular geometry, stereochemistry, conformation, and biomolecular structure and interactions
The Nuclear Overhauser Effect in Structural and Conformational Analysis, Second Edition, uniquely explains the NOE in detail, making it an indispensable resource for the novice as well as the experienced NMR researcher.
|Stereoselectivity in Synthesis
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Author: Tse-Lok Ho
Many chemicals are found in "right-" and "left-handed" forms that may react differently in the body. In planning a synthesis, chemists must know how to select the best method for making the preferred form of a chemical. This book shows how to choose the best method for a given synthesis. It provides readers with a thorough understanding of stereoselectivity in organic and medicinal chemistry as well as the pharmaceutical, agricultural, and food industries.
|The Anomeric Effect and Associated Stereoelectronic Effects (Acs Symposium Series)
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Brand: Brand: American Chemical Society
Discusses contemporary experimental and computational studies on the anomeric effect and related stereoelectronic effects and presents conflicting data and theories in this highly controversial area. Explores applications in carbohydrate chemistry, including enzymology, as well as organometallic chemistry and the chemistry of phosphates and sulfates. Includes examination of molecular modeling methods in compounds influenced by stereoelectronic effects.
- Used Book in Good Condition
|The CH-Pi Interaction: Evidence, Nature, and Consequences
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Author: Motohiro Nishio
A systematic exploration of the fascinating area of CH/p interaction-from the frontier of chemical research
The CH/p bond may be the weakest of the hydrogen bonds, but it has been found to play important roles in the physical, chemical, and biological properties of a variety of substances. This book offers a complete overview of the experimental basis, theoretical background, and nature of the CH/p interaction to facilitate a clearer common understanding of the interaction between CH bonds and p-systems. Featured topics include:
* Evidence and methods of detection
* Quantum chemical treatment of CH/p interaction
* Comparison with other types of weak molecular interactions
* Conformational consequences
* Chiroptical properties
* Selectivity in organic reactions
* Crystal structures of clathrates
* Inclusion compounds
* Interligand interactions in coordination chemistry
* Specific interactions in protein structures
* Prospects and possibilities for use in biochemistry and materials science
The CH/p Interaction makes an important contribution to the understanding of weak intermolecular forces and their potential value to the biochemical and pharmaceutical sciences. It will be welcomed by physical and synthetic organic chemists; structural chemists; and pharmaceutical and biochemists.
|Chirality in Natural and Applied Science
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An understanding of chirality is central to the study and application of the molecular sciences. Particularly relevant to the work of pharmaceutical, natural product, organic, and analytical chemists, biochemists, and molecular biologists, Chirality in Natural and Applied Science provides a highly practical overview of the chemical significance of chirality.
Contributions from world-class scientists describe our current understanding of chirality and discuss its significant impact on modern chemistry and molecular science. They explore the origins of chirality, its natural occurrence on a variety of scales, and its current and potential applications in research and industry.
Chirality undoubtedly will remain integral to all of molecular science, and as our knowledge and understanding grow, its importance certainly will increase. Bringing together the insights and experience of scientists who have played influential roles in chirality research, Chirality in Natural and Applied Science helps ensure a thorough understanding of chirality, its importance and its applications.
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